Answer:
No.
Systolic is the pressure exerted on the walls of the arteries when the heart is contracting.
Diastolic is the pressure exerted on the walls of the arteries when the heart is at rest.
Hence, since the contraction of the heart elevates the internal pressure of the circulatory system, it can never be exceeded by the diastolic pressure, since it is the lowest pressure that the circulatory system reaches during the cycle of a "heart-beat".