Yes you can. Extracts or flavorings are interchangeable, according to your taste.
Coffee powder or almond extract.
You can try any sweet syrup (most of them) just don't use honey
Extract in "vanilla extract" is simply the liquid extracted from the insides of a vanilla bean.
They're both flavorings, so as long as you don't mind the almond taste, why not?
yes, as long as the flavor you want to achieve is vanilla and not maple.
Alton Brown's Fruit Salad
Raw Vanilla Extract Recipe
How to Make Vanilla Extract
Vanilla Bundt Cake Recipe