The easiest way is to watch them urinate - if the urine comes from under the belly then they are male if they squat and the urine comes from under their tail then they are female.
Look under their tail and check to see if they have a scrotum with testicles between their back legs - or wait until they urinate if the urine comes from under their belly they are male.
I would be very careful about that, because Nubians are 200lbs, but smaller breeds do not mature larger then 115. If they get along well, and are completely out of sight of does, then you can try it,...