To group chat, when you are chatting with someone, press "options". Also, there is a button that says "group chat". Then you type in the third persons' gmail address.
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First, you have to make sure that someone is online. They have to be a gmail user. When the dot next to their name is green on the left side of your screen, just click on their name and a little...
Group chat allow you to chat with more then one people at the same time, using the same application. There are many websites which are offering "Group chat" But I would suggest you to check "Banckle...