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Club Soda. It's AMAZING!
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If it really is rust, you should be able to get some of the solution for removing rust from carpet. Brush that into the shirt colar then run the shirt through the washer to make sure you get it all out. Test the solution on a shirt-tail or other inconspicuous place to make sure it doesn't eat the shirt.
First answer by LeopoldGoenitz. Last edit by Redbeard. Contributor trust: 1699 [recommend contributor]. Question popularity: 19 [recommend question]
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