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With difficulty. Probably the best way is to try culturing the unknown organism on agar media amended with different antibiotics. Certain antibiotic combinations will prevent most true Fungi from growing while allowing oomycetes to grow (PARP is an example). In this case, you can see the colony growing without a microscope. But really, you need a microscope to be sure.

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Q: How does one tell apart fungi from members of the phylum Oomycota by using only the naked eye?
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