The equivalence point is the point where the number of moles of base equal the number of moles of acid. The end point is the point where the indicator being used changes color (also 'indication point)'.
If the indicator is chosen correctly, the end point will essentially be exactly as near as possible at the equivalence point.
The point of the titration is to find the equivalence point -- the end point is just a very close approximation to it. This is because the pH of the solution changes very rapidly close to the equivalence point.
Therefore, the indicator will change color very close to the equivalence point because of the steepness of the pH change.
Titration error is simply the difference between the end point of a titration and the equivalence point of it. It can mathematically defined as Error = Vol(End Point) - Vol(Equivalence Point)
These terms are synonyms.
when the equivalence point of a titration is achieved.. Added: (More precisely:) The equivalence point is the point where the number of moles of base equal the number of moles of acid. The end point is the point where the indicator being used changes color (also 'indication point)'. If the indicator is chosen correctly, the end point will essentially be exactly as near as possible at the equivalence point. The point of the titration is to find the equivalence point -- the end point is just a very close approximation to it. This is because the pH of the solution changes very rapidly close to the equivalence point. Therefore, the indicator will change color very close to the equivalence point because of the steepness of the pH change
Titration without indicator is only possible with another measurement:Examples / possibilities:pH-electrode measurement (acid-base titration)Conductivity measurement (acid-base titration or ion-reaction)Change of color by excess or depletion of the reactant/titrant (redox titration)Precipitation by excess or depletion of the reactant/titrantAdded:(The following was more or less written for 'indicator' titrations, but same principles count for other 'sharply' changing properties):The equivalence point is the point where the number of moles of titrant equal the number of moles of the reactant. The end point is the point where the indicator being used changes color (also 'indication point)'.If the indicator is chosen correctly, the end point will essentially be as near as possible at the equivalence point.The point of the titration is to find the equivalence point -- the end point is just a very close approximation to it. This is because the pH of the solution changes very rapidly close to the equivalence point.Therefore, the indicator will change color very close to the equivalence point because of the steepness of the pH change
The equivalence point is the point in a titration when the amount of added standard reagent is chemically equal to the amount of analyte. The end point is the point in a titration when a physical change occurring immediate after the equivalence point
Titration error is simply the difference between the end point of a titration and the equivalence point of it. It can mathematically defined as Error = Vol(End Point) - Vol(Equivalence Point)
The equivalence point is the point in a titration when the amount of added standard reagent is chemically equal to the amount of analyte. The end point is the point in a titration when a physical change occurring immediate after the equivalence point
These terms are synonyms.
The chemical process for back titration is to titrate the analyte past the original end point/equivalence point, and then BACK titrate the excess titrant to equivalence.
when the equivalence point of a titration is achieved.. Added: (More precisely:) The equivalence point is the point where the number of moles of base equal the number of moles of acid. The end point is the point where the indicator being used changes color (also 'indication point)'. If the indicator is chosen correctly, the end point will essentially be exactly as near as possible at the equivalence point. The point of the titration is to find the equivalence point -- the end point is just a very close approximation to it. This is because the pH of the solution changes very rapidly close to the equivalence point. Therefore, the indicator will change color very close to the equivalence point because of the steepness of the pH change
the end point will be a simple multiple of the first
the end point will be a simple multiple of the first
Titration without indicator is only possible with another measurement:Examples / possibilities:pH-electrode measurement (acid-base titration)Conductivity measurement (acid-base titration or ion-reaction)Change of color by excess or depletion of the reactant/titrant (redox titration)Precipitation by excess or depletion of the reactant/titrantAdded:(The following was more or less written for 'indicator' titrations, but same principles count for other 'sharply' changing properties):The equivalence point is the point where the number of moles of titrant equal the number of moles of the reactant. The end point is the point where the indicator being used changes color (also 'indication point)'.If the indicator is chosen correctly, the end point will essentially be as near as possible at the equivalence point.The point of the titration is to find the equivalence point -- the end point is just a very close approximation to it. This is because the pH of the solution changes very rapidly close to the equivalence point.Therefore, the indicator will change color very close to the equivalence point because of the steepness of the pH change
The equivalence point is the point in a titration when the amount of added standard reagent is chemically equal to the amount of analyte. The end point is the point in a titration when a physical change occurring immediate after the equivalence point
The pH at point of halfway titration is at pKa level (this even might be at pH above 7)andpH of equivalence point (end point) is not at pH = 7.0 , but (sometimes far) above 7.0.
to determine the end point of titration
In an acid-base titration for the reaction HCl + NaOH -> H2O + NaCl the equivalence point is when the hydrochloric acid and sodium hydroxide neutralise each other in equimolar proportions. When one mole of HCl is added to one mole of NaOH then equivalence point is reached.The 'end point' in a titration is when the indicator changes to the neutral colour (e.g. green) and this is usually an approximation of where the equivalence point is.As a result, we can deduce concentrations of unknown substances if we know the stoichiometric numbers of in the chemical reaction (i.e. 1HCl) and have a substance of known concentration react the unknown with.