You seem to have your thinking backwards. Nitrogen is "lighter" than air. And by lighter, I mean less dense. Air is essentially 79% nitrogen and 21% (There is technically Argon, carbon dioxide and...
No, although the most of air is nitrogen, pure N2 (28.0 g/mol) is lighter because the other 19% O2 (32.0 g/mol) is heavier. The 1% Ar (18 g/mol) alone cannot compensate that.
Density of Nitrogen and Air.
If you are asking whether nitrogen is less dense than air and will float on top of it, then yes, nitrogen is "lighter," albeit only slightly. More accurately, nitrogen,...