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It has to do with the energy level accessible to the electron in a particular type of bond or orbital. The difference between the two energy levels determines the energy of the quantum step and...
don't take them you frekin' moron
don't take them you frekin' moron
don't take them you frekin' moron
don't take them you frekin' moron
don't take them you frekin' moron
don't take them you...