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Fajans' method makes use of two facts regarding adorption effects on precipitates of a colloidal or semicolloidal state

1. finely divided precipitates tend to adsorb o their surface ions present in the solution. by doing so, the particles become electrically charged.

2. a preciptate tend to adsorb ions common to itself. thus, a precipitate of AgCl tend to adsorb Ag/Cl- in preference to forgeign ions like NO3 and Na.

Futhermore, the adsorption indicator used should not be too weakly or too strongly adsorbed by the precipitate. Otherwise, false endpoints could be observed.

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Q: What are the conditions of Fajans method in Precipitation Titration?
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