Blown head gaskets will most commonly cause a loss of coolant (anti-freeze) and as a result overheating of the engine. Another sympton could be water leaking into the oil which will give the oil a coffee with milk type appearance although this is much less common.
Addendum:
Also on the Chevy Venture a head gasket leak can develop such that exhaust fumes are pushed into the coolant system - the coolant will be displaced and expelled, first via the coolant reservoir then the van will overheat and dump the coolant right out of the pressure relief at the cap.
To test for this particular leak: when the engine is cold, remove the radiator cap, then start the vehicle. If coolant immediately start pouring from the top of the radiator, this could well be your problem.
I had this problem on my 2001 Chevy Venture and researched it on auto forums and found the answer in an obscure location. Just had the head gaskets replaced (along with the intake gaskets since this is also a common problem on these beasts) and everything is now good.