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It depends on what you're talking about. If you're just talking about unfilled water balloons, and you're putting them in a refrigerator, or a cooler, than nothing drastic should happen. Of course, effects will vary from material to material, but the temperature of a typical home freezer isn't enough to do anything major.

If you're talking about filled water balloons, then the situation is different. Recall that when water freezes, it expands. If the water balloon is filled up with too much water, it will eventually pop as the water freezes and expands, leaving the ice behind in the shape it froze in. If there isn't too much water in it, the balloon will simply expand with the water and will end up being rubber stretched around ice.

I hope that answers your question. ^_^

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Q: What happens to water balloons if you leave them over night in a cooler?
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