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It has the cis 1,4 isoprene structure.

(CH2 CH3 C = CH CH2)n

I hope its clear.

From the left : Two methyl groups bonded to one carbon atom which in turn has a double bond with another carbon atom. This carbon is again bonded to a methyl group and a hydrogen atom. This repeated n times gives the polymer - natural rubber.
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Q: What is the Structure of natural rubber?
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