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Phosphorus has 5 free bonding electrons. In PCl3, three of which bond to chlorine covalently this will give rise to a Pyramidal atomic arrangement even though its electronic arrangement is Tetrahedral. This Pyramidal Structure occurs due to the lone pair of electrons found on the Phosphorus. This will be the same type of bonding as in NH3 (ammonia). The only difference will be due to the larger size of phosphorus which will vary the bond angles. In NH3 the bond angles are of 107.5Degrees, in PCl3 the bond angles are slightly larger; approximately 109Degrees.

-Solange Mizzi

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12y ago
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11y ago

:Cl:

:P:Cl:

:Cl:

I can't show all the dots using a computer. There should be 2 between the top Cl and P and 2 between the lower Cl and P and the end Cl should have 2 aove it and 2 below it. The top Cl also needs 2 aove it and the bottom Cl needs 2 below it.

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14y ago

http://www.chemguide.co.uk/atoms/bonding/covalent.html

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13y ago

P in the middle with three cl's surrounding it and a lone pair on p i think

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Q: What is the electron dot-structure for PCl3?
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