Atomic number tells how many protons are inside an atom's nucleus and therefore also how many electrons the atom has. An atom's mass number is the number of protons AND neutrons in the atom's nucleus...
Deuterium, an isotope of hydrogen, has an atomic mass of 2 since it has a neutron as well as a proton in the nucleas. Hydrogen oxide, H20 is known as water - deuterium oxide is known as heavy water.