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It prevents the voltage spike that occurs when the magnetic lines of force cut across the solenoid windings when someone shuts the power off the solenoid. It is called inverse voltage and on a 12 volt coil, when you turn it off, the collapsing magnetic field can generate an inverse voltage of 200 volts or more for a split second. This is why sometimes you can get a "poke" out of a 12 volt system. It is the inverse voltage spike that causes a momentary shock to your fingers or body. (this momentary voltage is not harmful to a human). when a coil has a charge cause by applying DC and suddenly disconnected this charge will manifest as a voltage of opposite polarity across the coil the diode will clamp this charge to .6-.7 v removing reverse breakdown voltage present

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Q: What is the use of a diode in a solenoid?
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