Other contributors have said "Percentage of marriages that end in divorce?" is the same question as "What percentage of marriages end in divorce?" If you believe that these are not asking the same thing and should be answered differently, click here
I just had my pre-cana class and they said 50% of all marriages end in divorce. The number goes steeply higher as you re-marry (ie. 60% of second marriages and about 75% of 3rd marriages)....
It is difficult to come up with a statistic for "marriages with multiple children that end in divorce". See the several links provided below including a state-by-state chart for divorce rates...
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