Answer:
Democrat, Al Gore won the popular vote against George W. Bush in the 2000 election, but Bush won the electoral college vote. Neither candidate won a majority of the popular vote.
Samuel Tilden won the majority of the popular vote, but lost the electoral college vote to Rutherford B. Hayes in 1876,
Grover Cleveland won a plurality of popular vote in 1888 as did Andrew Jackson in 1824.