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The gas coming off is mostly or all carbon dioxide CO2. There is some evidence that when commercial baking soda is reacted with some vinegars, a very tiny (almost insignificant amount) of CO (carbon monoxide) may be co-generated. Again, if it is true, the amounts of CO are meaninglessly low. For all intensive purposes, the gas produced is CO2, the standard by which all greenhouse gasses are measured.

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Q: Where is the gas coming from when you mix vinegar and baking soda?
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A balloon containing vinegar and baking soda will inflate due to the formation of carbon dioxide gas from the chemical reaction between the vinegar and baking soda.


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