When I was a youngster and could not afford a magnifying glass, I would twist a piece of wire around a pencil so that it formed a round piece at the end of the wire. I would then dip the rounded end into water so that a blob of water made a very small magnifying glass.
I suspect that when it has rained this same effect is left on leaves, millions of tiny magnifying glasses all concentrating the suns rays onto what they happen to land on. Just one tiny focal point of a rain drop could possibly generate enough heat to start a fire.
Robert