Does heat expand rubber

Answer 1

Whether a material expands or contracts when it is heated can be ascribed to a property of the material called its entropy. The entropy of a material is a measure of the orderliness of the molecules that make up the material. When the molecules are arranged in an ordered fashion, the entropy of the material is low. When the molecules are in a disordered arrangement, the entropy is high. (An ordered arrangement can be thought of as coins in a wrapper, while a disordered one as coins in a tray.) When a material is heated, its entropy increases because the orderliness of its molecules decreases. This occurs because as a material is heated, its molecules move about more energetically. In materials made up of small, compact molecules, e.g., the liquid in a thermometer, as the molecules move about more, they push their neighbouring molecules away. Rubber, on the other hand, contains very large, threadlike molecules. When rubber is heated, the sections of the molecules move about more vigorously. In order for one part of the molecule to move more vigorously as it is heated, it must pull its neighbouring parts closer. To visualize this, think of a molecule of the stretched rubber band as a piece of string laid out straight on a table. Heating the stretched rubber band causes segments of the molecules to move more vigorously, which can be represented by wiggling the middle of the string back and forth. As the middle of the string moves, the ends of the string get closer together. In a similar fashion, the molecules of rubber become shorter as the rubber is heated, causing the stretched rubber band to contract

Answer 2

expands