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There are two reasons. One is that water molecules are able to form four hydrogen bonds each. This is a lot for a very small molecule. The more hydrogen bonds it has, the more energy (heat) it takes to strip it from its neighbours. The other (lesser) reason is that the difference in density between liquid water and steam vapour is huge compared with most substances, which means that as it vaporizes it must push against atmospheric pressure, to evolve (atmospheric pressure is trying to keep it confined as a liquid - this is why water boils at 68 degC (IIRC) on top of Everest (less resistance from atmospheric pressure)).

But really it is the hydrogen bonds, mostly. Which is also why water has an enormous surface tension....

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12y ago
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11y ago

The heat (enthalpy) of vaporization for water is defined as the heat per unit mass required to convert liquid water at its boiling point to gaseous water at the same temperature. For any given mass unit, the value for water is higher than that for almost any other liquid, because of the strong hydrogen bonding of water in liquid.

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Q: Why does water have a high latent heat of vapourisation?
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